KINETICS OF POLYMERIZATION OF METHYL-METHACRYLATE INITIATED WITH CYCLOHEXANONE .1.

被引：9
|
作者：
KAIM, A
机构：
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1984年 / 22卷 / 08期
关键词：
Catalysts - CHEMICAL REACTIONS - Reaction Kinetics - MONOMERS - Polymerization - Organic compounds - POLYMERIZATION - Catalysis;
D O I：
10.1002/pol.1984.170220811
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The kinetics of radical polymerization of methyl methacrylate were investigated in a dioxane solution with cyclohexanone as initiator. It was found that the overall rate of reaction initiated with cyclohexanone (R//p) is proportional to the concentration of monomer and to the square root of the concentration of the initiator. The effect of temperature on the R//p in the temperature range of 65-95 degree C was discussed. The Arrhenius activation energy E//a estimated for the temperature range of 65-75 degree C was 137 kJ mol** minus **1.
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页码：1891 / 1895
页数：5
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