Synthesis of metal silicide powders by thermolysis of metal chlorides with magnesium silicide

被引：14

作者：

Fitzmaurice, JC ^{[1
]}

Hector, AL ^{[1
]}

Parkin, IP ^{[1
]}

Rowley, AT ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL,CHRISTOPHER INGOLD LABS,DEPT CHEM,LONDON WC1H 0AJ,ENGLAND

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1995年 / 101卷 / 1-4期

关键词：

metal silicide; metal chlorides; magnesium silicide; powder diffraction; thermolysis;

D O I：

10.1080/10426509508042498

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thermolysis (850 degrees C) of a mixture of Mg2Si and MCl(n) (M = Y, Gd, Dy, Ho, Ti, Zr, Hf, Nb, Ta, Mo, W, Fe, Pr; n = 3, 4, 5) produces metal silicides M(x)Si(y) as microcrystalline powders. The reactions give a useful insight into the mechanisms working in this type of reaction.

引用

页码：47 / 55

页数：9

共 26 条

[1] MAGNETIC-PROPERTIES VERSUS CRYSTAL-STRUCTURE IN HEAVY RARE-EARTH SILICIDES RSI2-X [J].

AUFFRET, S ;

PIERRE, J ;

LAMBERTANDRON, B ;

MADAR, R ;

HOUSSAY, E ;

SCHMITT, D ;

SIAUD, E .

PHYSICA B, 1991, 173 (03) :265-276

[2] LOW-TEMPERATURE PRECURSOR SYNTHESIS OF CRYSTALLINE NICKEL DISULFIDE [J].

BONNEAU, PR ;

SHIBAO, RK ;

KANER, RB .

INORGANIC CHEMISTRY, 1990, 29 (13) :2511-2514

[3] RAPID SOLID-STATE SYNTHESIS OF MATERIALS FROM MOLYBDENUM-DISULFIDE TO REFRACTORIES [J].

BONNEAU, PR ;

JARVIS, RF ;

KANER, RB .

NATURE, 1991, 349 (6309) :510-512

[4]

BONNEAU PR, 1992, INORG CHEM, V31, P227

[5] SELF-PROPAGATING HIGH-TEMPERATURE SYNTHESIS [J].

CAHN, RW .

ADVANCED MATERIALS, 1990, 2 (6-7) :314-316

[6] ELECTRONIC PROPERTIES OF SILICON-TRANSITION METAL INTERFACE COMPOUNDS [J].

Calandra, C. ;

Bisi, O. ;

Ottaviani, G. .

SURFACE SCIENCE REPORTS, 1985, 4 (5-6) :271-364

[7] THE DISILICIDES OF TUNGSTEN, MOLYBDENUM, TANTALUM, TITANIUM, COBALT, AND NICKEL, AND PLATINUM MONOSILICIDE - A SURVEY OF THEIR THERMODYNAMIC PROPERTIES [J].

CHANDRASEKHARAIAH, MS ;

MARGRAVE, JL ;

OHARE, PAG .

JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1993, 22 (06) :1459-1468

[8] RAPID, LOW-ENERGY SYNTHESIS OF LANTHANIDE NITRIDES [J].

FITZMAURICE, JC ;

HECTOR, A ;

ROWLEY, AT ;

PARKIN, IP .

POLYHEDRON, 1994, 13 (02) :235-240

[9] LOW-TEMPERATURE ROUTES TO EARLY TRANSITION-METAL NITRIDES [J].

FITZMAURICE, JC ;

HECTOR, AL ;

PARKIN, IP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (16) :2435-2438

[10] INTERFACE CATALYTIC EFFECT - CR AT THE SI(111)-AU INTERFACE [J].

FRANCIOSI, A ;

WEAVER, JH ;

ONEILL, DG .

PHYSICAL REVIEW B, 1983, 28 (08) :4889-4892

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