MIXED-LIGAND CHELATE EXTRACTION OF NEODYMIUM(III) WITH THENOYLTRIFLUOROACETONE AND VARIOUS SULFOXIDES

被引：14

作者：

SANTHI, PB ^{[1
]}

REDDY, MLP ^{[1
]}

RAMAMOHAN, TR ^{[1
]}

DAMODARAN, AD ^{[1
]}

机构：

[1] CSIR,REG RES LAB,TRIVANDRUM 695019,INDIA

来源：

TALANTA | 1994年 / 41卷 / 01期

关键词：

D O I：

10.1016/0039-9140(94)80162-2

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Mixed-ligand chelate extraction of Nd(III) into benzene with mixtures of thenoyltrifluoroacetone (HTTA) and bis-2-ethylhexyl sulphoxide (B2EHSO) or di-n-octyl sulphoxide (DOSO) or diphenyl sulphoxide (DPhSO) or trioctylphosphine oxide (TOPO) from thiocyanate solutions has been studied. A very high synergistic enhancement of the order 10(3) has been observed in these systems. Thus this mixed-ligand chelate system may be useful in the extraction and separation of Nd(III) from other metal ions. The mechanism of extraction can be explained by a simple chemically based model presented in this paper.

引用

页码：9 / 14

页数：6

共 17 条

[11] HYDRATION AND AGGREGATION OF MONOFUNCTIONAL SULFOXIDE AND OTHER NEUTRAL OXYGEN-DONOR EXTRACTANTS - THE DI(2-ETHYLHEXYL) SULFOXIDE, DODECANE, WATER-SYSTEM [J].