MULTIPLE BONDS BETWEEN MAIN-GROUP ELEMENTS AND TRANSITION-METALS .122. METHYLTRIOXORHENIUM(VII) AS CATALYST FOR EPOXIDATIONS - STRUCTURE OF THE ACTIVE SPECIES AND MECHANISM OF CATALYSIS

被引：268

作者：

HERRMANN, WA

FISCHER, RW

SCHERER, W

RAUCH, MU

机构：

[1] Anorganisch-Chemisches Institut, Technischen Universität München, Garching, D-85747

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 08期

关键词：

D O I：

10.1002/anie.199311571

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Explosive in the solid state, the bis(eta2-peroxo) complex 1, which in solution is the active species in the epoxidation of olefins with [CH3ReO3]. could be characterized by X-ray crystallography as the diglyme adduct 2. Under catalytic conditions (excess of H2O2), 1 is far more stable than in the free state.

引用

页码：1157 / 1160

页数：4

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