THE SYNTHESIS, MOLECULAR-STRUCTURE AND INTERCONVERSION OF 2 NOVEL BENZENE-COORDINATED PENTARUTHENIUM CARBIDO CLUSTER ISOMERS [RU5C(CO)12(MU-3-ETA-2-ETA-2-ETA-2-C6H6)] AND [RU5C(CO)12(ETA-6-C6H6)]

被引：31
作者：
BAILEY, PJ
BRAGA, D
DYSON, PJ
GREPIONI, F
JOHNSON, BFG
LEWIS, J
SABATINO, P
机构：
[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND
[2] UNIV BOLOGNA,DIPARTIMENTO CHIM G CIAMICIAN,I-40126 BOLOGNA,ITALY
[3] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 02期
关键词：
D O I：
10.1039/c39920000177
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two isomers of a benzene-coordinated pentaruthenium-carbido cluster, [Ru5C(CO)12(mu(3):eta(2):eta(2):eta(2)-C6H5)] 1 and [Ru5C(CO)12(eta(6)-C6H6)] 2 have been synthesised from [Ru5C(CO)15] 3 and structrally characterised by single crystal X-ray diffraction; 1 is irreversibly converted to 2 on mild thermolysis.
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页码：177 / 178
页数：2
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