Crystal structure of trans-bis(diethanolamine-kappa O-3, N,O ') manganese(II) bis(3-aminobenzoate)

被引：4

作者：

Ibragimov, Aziz B. ^{[1
]}

Zakirov, Bakhtiyar S. ^{[1
]}

Ashurov, Jamshid M. ^{[2
]}

机构：

[1] Uzbek Acad Sci, Inst Gen & Inorgan Chem, M Ulugbek Str 77a, Tashkent 700170, Uzbekistan

[2] Acad Sci Uzbek, Inst Bioorgan Chem, M Ulugbek Str 83, Tashkent 700125, Uzbekistan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2016年 / 72卷

关键词：

crystal structure; coordination compound; 2-aminobenzoic acid; diethanolamine; Mn complex; hydrogen bonding;

D O I：

10.1107/S2056989016004072

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Reaction of m-aminobenzoic acid (MABA), diethanolamine (DEA) and MnCl2 center dot 4H(2)O led to the formation of the title salt, [Mn(C4H11NO2)(2)](C7H6NO2)(2). In the complex cation, the Mn2+ ion is located on an inversion centre and is coordinated by two symmetry-related tridentate DEA molecules, leading to the formation of a slightly distorted MnN2O4 octahedron. The MABA(-) counter-anions are connected to the complex ion by a pair of rather strong O-H center dot center dot center dot O hydrogen bonds, yielding a 1: 2 supramolecular aggregate. Much weaker N-H center dot center dot center dot O hydrogen bonds connect neighbouring aggregates into a three-dimensional network structure.

引用

页码：502 / +

页数：8

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