VINYL GLYCOSIDES IN OLIGOSACCHARIDE SYNTHESIS .1. A NEW LATENT-ACTIVE GLYCOSYLATION STRATEGY

被引：93

作者：

BOONS, GJ

ISLES, S

机构：

[1] School of Chemistry, The University of Birmingham, Edgbaston, Birmingham

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 21期

关键词：

D O I：

10.1016/S0040-4039(00)73249-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We have developed a never latent-active glycosylation strategy. This glycosylation strategy is based on isomerisation of substituted allyl glycosides to give vinyl glycosides which can subsequently be used in a Lewis acid mediated glycosylation reaction. This approach will enable complex oligosaccharides of biological importance to be prepared in a highly convergent manner.

引用

页码：3593 / 3596

页数：4

共 23 条

[1] DISPIROKETALS IN SYNTHESIS .5. A NEW OPPORTUNITY FOR OLIGOSACCHARIDE SYNTHESIS USING DIFFERENTIALLY ACTIVATED GLYCOSYL DONORS AND ACCEPTORS [J].