GROUND-STATE CONSTANTS AND K-TYPE DOUBLING FOR ALLENE

被引：14

作者：

HEGELUND, F ^{[1
]}

ANDRESEN, N ^{[1
]}

KOIVUSAARI, M ^{[1
]}

机构：

[1] UNIV OULU,DEPT PHYS,SF-90570 OULU,FINLAND

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1991年 / 149卷 / 01期

关键词：

D O I：

10.1016/0022-2852(91)90160-C

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The ground state rotational and centrifugal distortion constants of allene have been determined from a simultaneous analysis of GSCDs obtained from three infrared bands [F. Hegelund, R. Anttila, and S. Alanko, J. Mol. Spectrosc.141, 309-316 (1990)] and GSCDs obtained from the perpendicular bands ν9 and ν10. The effect of K-type doubling in the ground state has been observed in the KΔK = +2 and -2 subbands of ν9 and ν10, and the splitting constant d2 has been determined including its sign. © 1991.

引用

页码：305 / 313

页数：9

共 8 条

[1]

[Anonymous], 1982, MOL VIBRATIONAL ROTA

[2] L-RESONANCE PERTURBATIONS IN INFRARED PERPENDICULAR BANDS [J].