CAUDATOL, A GUAIANOLIDE FROM PERICOME-CAUDATA

被引：4

作者：

JOLAD, SD

HOFFMANN, JJ

BATES, RB

CALDERS, S

MCLAUGHLIN, SP

机构：

[1] UNIV ARIZONA,COLL PHARM,TUCSON,AZ 85721

[2] UNIV ARIZONA,DEPT CHEM,TUCSON,AZ 85721

来源：

PHYTOCHEMISTRY | 1990年 / 29卷 / 09期

关键词：

Asteraceae; caudatol; eupatoriopicrin; Helenieae; Pericome caudata; sesquiterpenoids;

D O I：

10.1016/0031-9422(90)87128-H

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

From the more polar fraction of the dichloromethane extract of the aerial parts of Pericome caudata, a new guaianolide, named caudatol, has been isolated and identified on the basis of spectroscopy as a derivative of eupatoriopicrin in which the C-8 side chain is further esterified at C-5′ by 3,4-dihydroxybut-2(5)enoic acid. © 1990.

引用

页码：3024 / 3028

页数：5

共 3 条

[1] GUAIANOLIDES FROM PERICOME-CAUDATA [J].

JOLAD, SD ;

HOFFMANN, JJ ;

TIMMERMANN, BN ;

BATES, RB ;

CAMOU, FA ;

MCLAUGHLIN, SP .

PHYTOCHEMISTRY, 1990, 29 (02) :649-652

[2]

SAMEK Z, 1969, TETRAHEDRON LETT, P2931

[3] CONFIGURATION OF ENDOCYCLIC DOUBLE-BOND AND CONFORMATION OF GERMACRANOLIDE DILACTONES, ISABELIN, ISOISABELIN, AND RELATED GERMACRANOLIDE MONOLACTONES, AS STUDIED BY NUCLEAR OVERHAUSER EFFECT [J].

TORI, K ;

HORIBE, I ;

YOSHIOKA, H ;

MABRY, TJ .

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1971, (06) :1084-&

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