THE EFFECT OF THE CHEMICAL-STRUCTURE OF CHAIN ENDS ON THE THERMAL-DEGRADATION OF POLYSTYRENE

被引：27
作者：
COSTA, L
CAMINO, G
GUYOT, A
BERT, M
CLOUET, G
BROSSAS, J
机构：
[1] CNRS,MAT ORGAN LAB,F-69390 VERNAISON,FRANCE
[2] CNRS,CTR RECH MACROMOLEC,F-67083 STRASBOURG,FRANCE
来源：
POLYMER DEGRADATION AND STABILITY | 1986年 / 14卷 / 01期
关键词：
POLYMERIZATION - POLYMERS - Molecular Structure;
D O I：
10.1016/0141-3910(86)90023-6
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A set of polystyrenes of comparable molecular weight around 4000, prepared by anionic polymerisation, were end-capped with various structures. Their thermal degradation behaviour (weight loss kinetics, nature and amount of volatile by-products) is governed by the nature of the chain ends. Some features of the degradation mechanisms are discussed.
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页码：85 / 93
页数：9
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