REACTIONS BETWEEN CERTAIN TRIALKOXYTUNGSTEN ALKYLIDYNE COMPLEXES AND CARBON-MONOXIDE - COMPETITIVE C-C BOND FORMATION LEADING TO ALKYNE OR KETENYL COMPLEXES

被引：19

作者：

CHISHOLM, MH ^{[1
]}

HO, D ^{[1
]}

HUFFMAN, JC ^{[1
]}

MARCHANT, NS ^{[1
]}

机构：

[1] INDIANA UNIV,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405

来源：

ORGANOMETALLICS | 1989年 / 8卷 / 07期

关键词：

D O I：

10.1021/om00109a009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：1626 / 1636

页数：11

共 29 条

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[7] REACTION BETWEEN BIS(BENZYL)TETRAISOPROPOXYDITUNGSTEN(W=W) AND BUT-2-YNE - W2(CH2PH)2(OPRI)4(ETA-2-C2ME2)2 AND W2(H)(OPRI)4(MU-CPH)(MU-C4ME4) - A TERMINAL METAL HYDRIDE WITH H-1-NMR RESONANCE 20 PPM DOWNFIELD OF ME4SI [J].

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[8] METAL ALKOXIDES - MODELS FOR METAL-OXIDES .5. COUPLING OF ALKYNE LIGANDS IN REACTIONS INVOLVING DITUNGSTEN HEXAALKOXIDES - AN ALTERNATIVE TO THE METATHESIS REACTION M=M+-C=C--]2M=C [J].

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[9] EVIDENCE FOR EQUILIBRIA BETWEEN MU-ALKYNE AND ALKYLIDYNE COMPLEXES OF TUNGSTEN ALKOXIDES - [W2(OR)6(MU-C2R2')] REVERSIBLE MU2[(RO)3W=CR'] [J].

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[10] CARBONYLATION OF (BUTO)3W=CNME2 AND (PRIO)3(PY)2W=CNME2 (PY = PYRIDINE) - 2 DIFFERENT MODES OF CARBON CARBON BOND FORMATION [J].

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HUFFMAN, JC ;

MARCHANT, NS .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (09) :717-718

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