ELECTROCATALYTIC REDUCTION OF CARBON-DIOXIDE TO METHANOL .6. USE OF A SOLAR-CELL AND COMPARISON WITH THAT OF CARBON-MONOXIDE

被引：43

作者：

OGURA, K

YOSHIDA, I

机构：

[1] Department of Applied Chemistry, Yamaguchi University, Ube

来源：

ELECTROCHIMICA ACTA | 1987年 / 32卷 / 08期

关键词：

CARBON MONOXIDE - Reduction - CATALYSIS - ELECTROCHEMISTRY - METHANOL - Production - SALTS - Oxidation;

D O I：

10.1016/0013-4686(87)80033-6

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Carbon monoxide and carbon dioxide have been catalytically reduced by the surface-confined Everitt's salt and leucoindigo. The conversions are the redox reactions consisting of the reduction of CO or CO2 to methanol and the oxidation of Everitt's salt to Prussian blue or leucoindigo to indigo. These reactions need to be activated via the homogeneous catalysis involving a metal complex and a primary alcohol. Everitt's salt and leucoindigo were regenerated by using sunlight as the only energy source. The maximum current efficiencies were 96.5% for CO and 64.8% for CO2 at the cell voltage of 2.0 V. © 1987.

引用

页码：1191 / 1195

页数：5

共 10 条

[1]

DENISE B, 1982, CHEMTECH, P108

[2] ELECTROCATALYTIC REDUCTION OF CARBON-DIOXIDE TO METHANOL .3. USE OF AN ELECTROCHEMICAL PHOTOCELL [J].