A review on differential scanning calorimetry technique and its importance in the field of energetic materials

被引:35
作者
Abd-Elghany, Mohamed [1 ]
Klapoetke, Thomas M. [1 ]
机构
[1] Ludwig Maximilians Univ Munchen, Dept Chem, D-81377 Munich, Germany
关键词
differential scanning calorimetry; energetic materials; thermoanalysis;
D O I
10.1515/psr-2017-0103
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Differential scanning calorimetry (DSC) helps to follow processing conditions, since it is relatively easy to fingerprint the thermal behavior of materials. DSC instrument nowadays became a routine technique, which can be found virtually in every chemical characterization laboratory. The sample can be analyzed over a wide temperature range using various temperature programs under isothermal and non-isothermal conditions. It is appropriate to determine the kinetic parameters under non-isothermal conditions. The sample can be in many different physical forms and in various shapes (powder, granules, fiber, etc.). A lot of characterization (step/-glass transition, melting, and decomposition temperature, etc.) data can be obtained by easy way and within short time. DSC is very helpful in analysis of energetic materials due to very small amount of material is enough to run the experiment.
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页数:14
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共 46 条
[1]   Thermal Behavior and Decomposition Kinetics of Bis(2,2,2-trinitroethyl)-oxalate as a High Energy Dense Oxidizer and its Mixture with Nitrocellulose [J].
Abd-Elghany, Mohamed ;
Klapotke, Thomas M. ;
Elbeih, Ahmed .
PROPELLANTS EXPLOSIVES PYROTECHNICS, 2017, 42 (12) :1373-1381
[2]   Investigation of 2,2,2-trinitroethyl-nitrocarbamate as a high energy dense oxidizer and its mixture with Nitrocellulose (thermal behavior and decomposition kinetics) [J].
Abd-Elghany, Mohamed ;
Klapoetke, Thomas M. ;
Elbeih, Ahmed .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2017, 128 :397-404
[3]   Investigation of different thermal analysis techniques to determine the decomposition kinetics of ε-2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane with reduced sensitivity and its cured PBX [J].
Abd-Elghany, Mohamed ;
Klapoetke, Thomas M. ;
Elbeih, Ahmed ;
Zeman, Svatopluk .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2017, 126 :267-274
[4]  
Abd-Elghany Mohamed, 2017, [火炸药学报, Chinese Journal of Explosives & Propellants], V40, P24
[5]   Thermal Behavior and Decomposition Kinetics of RDX and RDX/HTPB Composition Using Various Techniques and Methods [J].
Abd-Elghany, Mohamed ;
Elbeih, Ahmed ;
Hassanein, Saeed .
CENTRAL EUROPEAN JOURNAL OF ENERGETIC MATERIALS, 2016, 13 (03) :714-735
[6]  
Bair HE, 1984, THERMAL CHARACTERIZA
[7]   Thermal ageing of rocket propellant formulations containing ε-HNIW (ε-CL20) investigated by heat generation rate and mass loss [J].
Bohn, MA .
THERMOCHIMICA ACTA, 2003, 401 (01) :27-41
[8]  
Brown ME, 2001, INTRO THERMAL ANAL T
[9]   DSC confirmation that vitrification is not necessary for stabilization of the restriction enzyme EcoRI dried with saccharides [J].
Buera, MP ;
Rossi, S ;
Moreno, S ;
Chirife, J .
BIOTECHNOLOGY PROGRESS, 1999, 15 (03) :577-579
[10]   Kinetics of thermal degradation of explosive binders Viton A, Estane, and Kel-F [J].
Burnham, AK ;
Weese, RK .
THERMOCHIMICA ACTA, 2005, 426 (1-2) :85-92