MILLIMETER-WAVE SPECTRUM OF GERMANIUM DICHLORIDE GECL2 - EQUILIBRIUM STRUCTURE AND ANHARMONIC-FORCE FIELD

被引：20

作者：

TSUCHIYA, MJ ^{[1
]}

HONJOU, H ^{[1
]}

TANAKA, K ^{[1
]}

TANAKA, T ^{[1
]}

机构：

[1] KYUSHU UNIV 33,FAC SCI,DEPT CHEM,HIGASHI KU,FUKUOKA 81281,JAPAN

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1995年 / 352卷

关键词：

D O I：

10.1016/0022-2860(95)08830-O

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The millimeter-wave spectrum of germanium dichloride GeCl2 produced in a glow discharge of germanium tetrachloride was observed for several isotopic species in the ground and vibrationally excited states, nu(1), nu(2), 2 nu(2), and nu(3). The analysis of the rotational spectra yielded the equilibrium molecular structure, r(e) = 2.169452(15) Angstrom and theta(e) = 99.882 5(15)degrees, and the harmonic and anharmonic force constants up to the third order.

引用

页码：407 / 415

页数：9

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