CARBON-CARBON BOND FORMATION VIA N-TOSYLIMINIUM IONS

被引：55

作者：

AHMAN, J ^{[1
]}

SOMFAI, P ^{[1
]}

机构：

[1] LUND INST TECHNOL, CTR CHEM, POB 124, S-22100 LUND, SWEDEN

来源：

TETRAHEDRON | 1992年 / 48卷 / 43期

关键词：

D O I：

10.1016/S0040-4020(01)88321-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Addition of carbon nucleophiles to cyclic N-tosyliminium ions, derived from alpha-hydroxy and alpha-methoxy tosylamides (5a,b and 6a,b, respectively) is described. In general, good to excellent yields were obtained when allyltrimethylsilane, 1-(t)butyldimethylsilyloxy-1-ethoxyethane, and trimethylsilyl cyanide were used as nucleophiles.

引用

页码：9537 / 9544

页数：8

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