DETERMINATION OF ALPHAMETHRINE AND CYPERMETHRINE IN WATER AND SOIL BY CAPILLARY ISOTACHOPHORESIS

被引:17
作者
DOMBEK, V [1 ]
STRANSKY, Z [1 ]
机构
[1] PALACKY UNIV, FAC NAT SCI, DEPT ANALYT & ORGAN CHEM, CS-77146 OLOMOUC, CZECHOSLOVAKIA
关键词
ELECTROPHORESIS; ALPHAMETHRINE; CYPERMETHRINE; PESTICIDES; PYRETHROID INSECTICIDES; SOILS; WATERS;
D O I
10.1016/0003-2670(92)85328-4
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A method for the isotachophoretic determination of the pyrethroid insecticides alphamethrine and cypermethrine in water and soil is described. After extraction of the insecticides from the samples and evaporation of solvents, alkaline hydrolysis (pH = 12, 50-degrees-C) was applied. The degradation products, cis- and trans-dichlorochrysanthemic acids, were identified and determined by capillary isotachophoresis.
引用
收藏
页码:69 / 73
页数:5
相关论文
共 22 条
[1]  
AMOS R, 1986, P BR CROP C PESTS DI, V1, P97
[2]  
ANDREWS TL, 1974, PESTIC MONIT J, V8, P50
[3]   THE LAMINAR-FLOW TORCH FOR GAS-CHROMATOGRAPHIC HE MICROWAVE PLASMA DETECTION OF PYRETHROIDS AND DIOXINS [J].
BRUCE, ML ;
CARUSO, JA .
APPLIED SPECTROSCOPY, 1985, 39 (06) :942-949
[4]   AN INFRARED SPECTROPHOTOMETRIC METHOD FOR DETERMINATION OF PYRETHRIN 2 [J].
BYRNE, JHN ;
MITCHELL, W ;
TRESADER.FH .
ANALYST, 1965, 90 (1071) :362-&
[5]   COLORIMETRIC DETERMINATION OF PYRETHRINS, ALLETHRIN, AND FURETHRIN [J].
CUETO, C ;
DALE, WE .
ANALYTICAL CHEMISTRY, 1953, 25 (09) :1367-1369
[6]   STUDY OF ALKALINE-HYDROLYSIS OF THE INSECTICIDE ALPHAMETHRINE BY ISOTACHOPHORETIC DETERMINATION OF DECOMPOSITION PRODUCTS [J].
DOMBEK, V ;
STRANSKY, Z .
JOURNAL OF CHROMATOGRAPHY, 1989, 470 (01) :235-240
[7]  
DOMBEK V, 1988, CHEM LISTY, V82, P1163
[8]  
DOMBEK V, 1985, ACTA UPOL FAC RER 27, V91, P153
[9]   DETERMINATION OF FMC 33297 RESIDUES IN PLANT, ANIMAL, AND SOIL MATRICES BY GAS-CHROMATOGRAPHY [J].
FUJIE, GH ;
FULLMER, OH .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1978, 26 (02) :395-398
[10]  
GRAHAM LR, 1965, OFFICIAL METHODS ANA