[H2RU6(CO)16(MU-C6H4O)] - BINDING OF 5 METAL ATOMS TO A PHENOL MOLECULE

被引：12

作者：

BOHLE, DS ^{[1
]}

VAHRENKAMP, H ^{[1
]}

机构：

[1] UNIV FREIBURG,INST ANORGAN & ANALYT CHEM,ALBERTSTR 21,W-7800 FREIBURG,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 02期

关键词：

D O I：

10.1002/anie.199001981

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The aromatic ligand of the title compound is linked to the Ru6 unit through η6 ‐aryl and μ‐OR coordination as well as an MCM three‐center bond (see picture at the right). Noteworthy are the high “loading” of the ligand with metal atoms and the fact that multiple coordination can also stabilize a very open metal arrangement. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：198 / 199

页数：2

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