TIXZRYC12 AND TIXHFYC12 (X+Y=8) - BINARY METAL METALLOCARBOHEDRENES

被引：64
作者：
CARTIER, SF
MAY, BD
CASTLEMAN, AW
机构：
[1] Department of Chemistry, Pennsylvania State University, University Park
来源：
JOURNAL OF CHEMICAL PHYSICS | 1994年 / 100卷 / 07期
关键词：
D O I：
10.1063/1.467154
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We report the production of binary metal metallocarbohedrenes. Direct laser vaporization of mixtures of zirconium or hafnium powders with titanium carbide yield the species TixZryC12 and TixHfyC12 (x+y=8). These results are discussed in the context of recent theoretical models addressing the stabilities and structures of the metallocarbohedrenes, their formation mechanism and possible implications for the synthesis of ''doped'' metallocarbohedrenes.
引用
收藏
页码：5384 / 5386
页数：3
相关论文
共 19 条
  • [1] PRODUCTION OF METALLO-CARBOHEDRENES IN THE SOLID-STATE
    CARTIER, SF
    CHEN, ZY
    WALDER, GJ
    SLEPPY, CR
    CASTLEMAN, AW
    [J]. SCIENCE, 1993, 260 (5105) : 195 - 196
  • [2] CARTIER SF, IN PRESS CHEM PHYS L
  • [3] STABILITY, BONDING, AND GEOMETRIC STRUCTURE OF TI8C12, TI8N12, V8C12, AND ZR8C12
    CHEN, H
    FEYEREISEN, M
    LONG, XP
    FITZGERALD, G
    [J]. PHYSICAL REVIEW LETTERS, 1993, 71 (11) : 1732 - 1735
  • [4] Cotton F. A., 1988, ADV INORG CHEM, P776
  • [5] LARGE CARBON CLUSTER ION FORMATION BY LASER ABLATION OF POLYIMIDE AND GRAPHITE
    CREASY, WR
    BRENNA, JT
    [J]. CHEMICAL PHYSICS, 1988, 126 (2-3) : 453 - 468
  • [6] DANCE I, 1992, J CHEM SOC CHEM COMM, V1779
  • [7] METALLO-CARBOHEDRENES [M8C12+ (M = V, ZR, HF, AND TI)] - A CLASS OF STABLE MOLECULAR CLUSTER IONS
    GUO, BC
    WEI, S
    PURNELL, J
    BUZZA, S
    CASTLEMAN, AW
    [J]. SCIENCE, 1992, 256 (5056) : 515 - 516
  • [8] TI8C12+-METALLO-CARBOHEDRENES - A NEW CLASS OF MOLECULAR CLUSTERS
    GUO, BC
    KERNS, KP
    CASTLEMAN, AW
    [J]. SCIENCE, 1992, 255 (5050) : 1411 - 1413
  • [9] ELECTRONIC-STRUCTURE AND BONDING IN THE METALLOCARBOHEDRENE TI8C12 (VOL 70, PG 29, 1993)
    METHFESSEL, M
    VANSCHILFGAARDE, M
    SCHEFFLER, M
    [J]. PHYSICAL REVIEW LETTERS, 1993, 71 (01) : 209 - 209
  • [10] PRODUCTION OF LARGE CARBON CLUSTER IONS BY LASER VAPORIZATION
    OKEEFE, A
    ROSS, MM
    BARONAVSKI, AP
    [J]. CHEMICAL PHYSICS LETTERS, 1986, 130 (1-2) : 17 - 19
12