TIXZRYC12 AND TIXHFYC12 (X+Y=8) - BINARY METAL METALLOCARBOHEDRENES

被引：64

作者：

CARTIER, SF

MAY, BD

CASTLEMAN, AW

机构：

[1] Department of Chemistry, Pennsylvania State University, University Park

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 100卷 / 07期

关键词：

D O I：

10.1063/1.467154

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report the production of binary metal metallocarbohedrenes. Direct laser vaporization of mixtures of zirconium or hafnium powders with titanium carbide yield the species TixZryC12 and TixHfyC12 (x+y=8). These results are discussed in the context of recent theoretical models addressing the stabilities and structures of the metallocarbohedrenes, their formation mechanism and possible implications for the synthesis of ''doped'' metallocarbohedrenes.

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页码：5384 / 5386

页数：3

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