PHOTOCHROMISM OF ALKYLISOPHTHALALDEHYDES IN THE SOLID-STATE - STRUCTURE REACTIVITY CORRELATIONS

被引：12

作者：

KUMAR, VA ^{[1
]}

VENKATESAN, K ^{[1
]}

机构：

[1] INDIAN INST SCI,DEPT ORGAN CHEM,BANGALORE 560012,KARNATAKA,INDIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1991年 / 06期

关键词：

D O I：

10.1039/p29910000829

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The crystal and molecular structures of the photochromic compounds 2,5-dimethylisophthalaldehyde (I) and 5-isopropyl-2-methylisophthalaldehyde (II) have been determined by single crystal X-ray analyses. The intramolecular gamma-hydrogen abstraction process involved in the photoenolisation of I and II in the solid state has been rationalised in the light of relevant geometrical parameters.

引用

页码：829 / 834

页数：6

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