HYDROGEN TEMPERATURE-PROGRAMMED REDUCTION BASED ON WATER ANALYSIS - APPLICATION TO VANADIUM PENTOXIDE

被引：13

作者：

BALLIVETTKATCHENKO, D ^{[1
]}

DELAHAY, G ^{[1
]}

机构：

[1] INST NATL POLYTECH TOULOUSE,F-31077 TOULOUSE,FRANCE

来源：

JOURNAL OF THERMAL ANALYSIS | 1994年 / 41卷 / 05期

关键词：

HETEROGENEOUS CATALYSIS; TEMPERATURE PROGRAMMED REDUCTION; V2O5; WATER ANALYSIS;

D O I：

10.1007/BF02547203

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Profiles of temperature programmed reduction (TPR) of V2O5 under H-2 have been studied through water analysis. This new approach enhances the sensitivity of the method. The influence of experimental parameters on the temperature corresponding to the maximum reduction rate, T(m), has been studied. The hydrogen concentration and heating rate are the two major factors that influence T(m). In our method, the amount of solid and the flow rate are also important fact n monitoring of profile distortions attributed to water condensation at the outlet of the reactor. An approach of the mechanism of reduction of V2O5 has been carried out. The best kinetic model which describes the reduction process is the Avrami-Erofeev tridimensional nucleation model.

引用

页码：1141 / 1151

页数：11

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