3-O-DEMETHYLSWERTIPUNICOSIDE FROM SWERTIA-PUNICEA

被引:17
作者
TAN, P [1 ]
HOU, CY [1 ]
LIU, YL [1 ]
LIN, LJ [1 ]
CORDELL, GA [1 ]
机构
[1] UNIV ILLINOIS,COLL PHARM,DEPT MED CHEM & PHARMACOGNOSY,PROGRAM COLLABORAT RES PHARMACEUT SCI,CHICAGO,IL 60612
关键词
SWERTIA-PUNICEA; GENTIANACEAE; BISXANTHONE C-GLYCOSIDE; 3-O-DEMETHYLSWERTIPUNICOSIDE; SELECTIVE INEPT NMR SPECTROSCOPY;
D O I
10.1016/0031-9422(92)80465-Q
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
A novel bisxanthone C-glycoside, 3-O-demethylswertipunicoside, structurally related to swertipunicoside, was isolated from whole plants of Swertia punicea. Determination of its structure was based on the interpretation of the spectroscopic data, particularly selective INEPT NMR spectra, and characterized as 1,3,5,8-tetrahydroxy-7-(1',3',6',7'-tetrahydroxy-9'-oxo-4'-xanthyl) xanthone 2'-C-beta-D-glucopyranoside.
引用
收藏
页码:4313 / 4315
页数:3
相关论文
共 8 条
[2]   ONE-DIMENSIONAL PROTON-CARBON CORRELATIONS FOR THE STRUCTURE DETERMINATION OF NATURAL-PRODUCTS [J].
CORDELL, GA ;
KINGHORN, AD .
TETRAHEDRON, 1991, 47 (22) :3521-3534
[3]   Selective INEPT Spectroscopy-A Powerful Tool for the Spectral Assignment and Structure Elucidation of Natural Products [J].
Cordell, Geoffrey A. .
PHYTOCHEMICAL ANALYSIS, 1991, 2 (02) :49-59
[4]  
HARBORNE JB, 1982, FLAVONOIDS ADV RES, P48
[5]  
Song WZ, 1986, ZHONG YAO TONG BAO, V11, P643
[6]   SWERTIPUNICOSIDE - THE 1ST BISXANTHONE C-GLYCOSIDE [J].
TAN, P ;
HOU, CY ;
LIU, YL ;
LIN, LJ ;
CORDELL, GA .
JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (25) :7130-7133
[7]  
1977, DICT CHINESE TRADITI
[8]  
1988, FLORA CHINA, P344