THERMODYNAMICS OF THE ELECTROCAPILLARITY OF OIL-WATER INTERFACES

被引：44

作者：

KAKIUCHI, T ^{[1
]}

SENDA, M ^{[1
]}

机构：

[1] KYOTO UNIV,FAC AGR,DEPT AGR CHEM,SAKYO KU,KYOTO 606,JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1983年 / 56卷 / 10期

关键词：

ELECTROCHEMISTRY;

D O I：

10.1246/bcsj.56.2912

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

General electrocapillary equations for the interfaces between two immiscible or partially miscible electrolyte solutions have been derived. The theory includes both nonpolarized and ideal polarized interfaces. The electrocapillary equation for the latter has been derived from the equation for the former as a special case where no common ionic species are distributed between the two phases. Implications of the general electrocapillary equation for oilwater interfaces are indicated.

引用

页码：2912 / 2918

页数：7

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