KINETICS OF THE INITIAL STEP OF CATALYTIC RADICAL-CHAIN OXIDATION OF CUMENE, INCLUDING CATALYST DEACTIVATION STEP

被引:0
|
作者
OPEIDA, IA [1 ]
ZALEVSKAYA, NM [1 ]
VASILIEV, AY [1 ]
机构
[1] LM LITVINENKO INST PHYSICOORGAN CHEM & COAL CHEM,DONETSK,UKRAINE
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中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A method has been developed for estimating the reaction rate constants of deactivation of an autocatalytic free radical-chain process catalyst in the presence of low-stability catalysts. Its applicability has been exemplified by tetralkylammonium halide-catalyzed cumene oxidation.
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页码:69 / 74
页数:6
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