REACTIONS OF SULFINYLATED RADICALS STEREOSELECTIVITY IN 6-MEMBERED RINGS

被引：0
|
作者：
RENAUD, P
机构：
来源：
HELVETICA CHIMICA ACTA | 1991年 / 74卷 / 06期
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D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The allylation and deuteration of six-membered cyclic sulfinylated radicals were investigated. For this purpose, radicals with the predefined conformations I and II were generated from 2-(phenylselenenyl)thiacyclohexane-1-oxide derivatives 7-10 (Scheme). Steric effects were insufficient to account for all the observed selectivities. The participation of stereoelectronic effects are envisaged to explain the stereoselective axial deuteration of type-II radicals.
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页码：1305 / 1313
页数：9
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