REACTIONS OF [ET3NH][(MU-CO)(MU-RS)FE2(CO)6] COMPLEXES WITH THIAZOLYL-MERCURIALS, OXAZOLYL-MERCURIALS AND IMIDAZOYL-MERCURIALS - A ROUTE TO FE2(CO)6 COMPLEXES CONTAINING AN ETA(1), ETA(2)-C=N BRIDGE

被引：14

作者：

SEYFERTH, D

ANDERSON, LL

DAVIS, WM

机构：

[1] Department of Chemistry, Massachusetts Institute of Technology, Cambridge

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 459卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0022-328X(93)86080-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of complexes of type [Et3NH][(mu-CO)(mu-RS)Fe2(CO)6] with thiazolyl-, oxazolyl- and N-methylimidazolylmercurials gave products of type in moderate yield, as well as (mu-RS)2Fe2(CO)6 and elemental mercury. The crystal structure of 13b [GRAPHICS] (Z = S, R = Et, R1 = H) is described: space group P1BAR (No. 2), a = 9.3478(6) angstrom, b = 1.4594(6) angstrom, c = 8.1005(4) angstrom, alpha = 97.511(5)-degrees, beta = 108.221(5), gamma = 71.516(5)-degrees, Z = 2, R = 0.060, R(W) = 0.064 for 2552 observed reflections.

引用

页码：271 / 281

页数：11

共 27 条

[1]

BERAUD J, 1962, B SOC CHIM FR, P2072

[2] STRUCTURAL STUDIES ON OSMIUM CARBONYL HYDRIDES .26. CRYSTAL-STRUCTURE OF A COMPLEX WITH A 2-METHYLIMIDAZOLYL LIGAND BOUND TO A TRIOSIUM CLUSTER - (MU-H)OS3(CO)10[MU-3,4-ETA-2-C3N2H2(2-CH3)] [J].