ASYMMETRIC HETERO-DIELS-ALDER REACTION CATALYZED BY STABLE AND EASILY PREPARED CAB CATALYSTS

被引：52

作者：

GAO, QZ ^{[1
]}

ISHIHARA, K ^{[1
]}

MARUYAMA, T ^{[1
]}

MOURI, M ^{[1
]}

YAMAMOTO, H ^{[1
]}

机构：

[1] NAGOYA UNIV,SCH ENGN,NAGOYA,AICHI 46401,JAPAN

来源：

TETRAHEDRON | 1994年 / 50卷 / 04期

关键词：

D O I：

10.1016/S0040-4020(01)80812-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A stable chiral (acyloxy)borane (CAB) complex is prepared in situ by mixing a tartaric acid derivative and arylboronic acids at room temperature. A solution of the catalyst is effective in catalyzing hetero Diels-Alder reactions to produce dihydropyrone derivatives of high optical purities.

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收藏

页码：979 / 988

页数：10

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