SYNTHESIS AND CHARACTERIZATION OF BINUCLEAR ARYLTHIOLATO-BRIDGED AND PHENYLSELENOLATO-BRIDGED ORGANOPLATINUM(II) COMPLEXES - CRYSTAL-STRUCTURE OF [PT2PH2(MU-SPH)2(PME2PH)2]

被引：22

作者：

JAIN, VK

KANNAN, S

BUTCHER, RJ

JASINSKI, JP

机构：

[1] BHABHA ATOM RES CTR,DIV FUEL CHEM,BOMBAY 400085,INDIA

[2] HOWARD UNIV,DEPT CHEM,WASHINGTON,DC 20059

[3] KEENE STATE COLL,KEENE,NH 03431

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 468卷 / 1-2期

关键词：

PLATINUM; THIOLATE; SELENOLATE; ARYL;

D O I：

10.1016/0022-328X(94)80062-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Binuclear organoplatinum(II) complexes of the type [Pt2Ar2(mu-EAr')2(PR3)2] (Ar = Ph or p-tol; E = S or Se; Ar'= Ph or p-tol; PR3 = PPr3 PBu3 or PMe2Ph) have been synthesized and characterized by elemental analysis and nuclear magnetic resonance (H-1 and P-31) spectroscopy. Some of these complexes were isolated exclusively as the trans isomer, but others were present at a mixture of cis and trans isomers. An X-ray diffraction study of [Pt2Ph2(mu-SPh)2(PMe2Ph)2] has shown that it has sym-trans geometry, with a planar four-membered Pt2S2 ring.

引用

页码：285 / 290

页数：6

共 25 条

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[22] EFFECTS OF SULFUR SUBSTITUENTS ON THE GEOMETRIES OF DIPALLADIUM MU-THIOLATO COMPLEXES - CRYSTAL-STRUCTURES OF PD2CL2(MU-CL)(MU-SR)(PME3)2 (R = ME, T-BU AND PH) AND PD2CL2(MU-SPH)2(PET3)2 [J].