AQUEOUS PHASE SYNTHESIS OF DICARBOXYLIC DERIVATIVES OF TITANOCENE

被引：0

作者：

WANG, ZQ ^{[1
]}

LU, SW ^{[1
]}

GUO, HF ^{[1
]}

LU, ZR ^{[1
]}

ZHOU, YK ^{[1
]}

机构：

[1] LANZHOU UNIV,DEPT CHEM,LANZHOU 730000,PEOPLES R CHINA

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1992年 / 22卷 / 07期

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D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The nine complexes, (RC5H4)2Ti(O2CC6H4X)2 (R=H, CH3; X=H, o-Cl, o-OH, o-NH2, o-NHPh), have been conveniently prepared by the reaction of (RC5H4) 2TiCl2 with 2 equiv. sodium salts of appropriate carboxylic acids in water containing acetylacetone. They have been characterized by elemental analysis, IR and H-1-NNR. The carboxylate ligands in the complexes coordinate to titanium atom in monodentate mode. The complexes contain functional groups (OH, NH2, NHPh), which are involved in strong intramolecular hydrogen-bonding.

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页码：883 / 892

页数：10

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