EFFECT OF METAL-OXIDES ON THE KINETICS OF THERMAL OXIDATIVE-DEGRADATION OF NYLON-6

被引：19

作者：

GUPTA, MC

JAIS, AT

机构：

[1] Chemistry Department, Nagpur University, Nagpur

来源：

THERMOCHIMICA ACTA | 1993年 / 230卷

关键词：

D O I：

10.1016/0040-6031(93)80357-G

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The rate constants and kinetic parameters for the thermal oxidative degradation of nylon-6 in the presence of metal oxides show the existence of a true kinetic compensation effect. This pattern of behaviour amongst metal oxides in the oxdiative degradation of nylon-6 has been linked to the higher oxidation state. The behaviour suggests that the reaction follows a redox or electron transfer mechanism due to tunnelling of electrons.

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页码：155 / 165

页数：11

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