SYNTHESIS AND CRYSTAL-STRUCTURE OF A NOVEL TETRANUCLEAR COMPLEX OF GOLD(I) WITH O-CARBORANE DERIVATIVES AS LIGANDS

被引：39
|
作者：
CRESPO, O
GIMENO, MC
JONES, PG
LAGUNA, A
机构：
[1] UNIV ZARAGOZA,CSIC,INST CIENCIA MAT ARAGON,DEPT QUIM INORGAN,E-50009 ZARAGOZA,SPAIN
[2] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ANORGAN & ANALYT CHEM,D-38023 BRAUNSCHWEIG,GERMANY
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 22期
关键词：
D O I：
10.1039/c39930001696
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Treatment of the dinuclear complex [(AuCl)2(B10H10C2(PPh2)2}] in dichloromethane with 1,2-dimercapto-1,2-dicarba-closo-dodecarborane and Na2CO3 results in the formation of the tetranuclear complex [Au4(S2C2B10H10)2{(PPh2)2C2B10H10)2]; the structure was confirmed by X-ray studies and shows an eight-membered Au4S4 ring with a short transannular gold-gold interaction,
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页码：1696 / 1697
页数：2
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