[CU44SE22(PET(2)PH)(18)] AND [CU44SE22(PNBUTBU(2))(12)] - SYNTHESIS AND STRUCTURE OF 2 COPPER CLUSTERS WITH ISOMERIC CU-SE FRAMEWORKS

被引：34

作者：

DEHNEN, S ^{[1
]}

FENSKE, D ^{[1
]}

机构：

[1] UNIV KARLSRUHE,INST ANORGAN CHEM,D-76131 KARLSRUHE,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 22期

关键词：

D O I：

10.1002/anie.199422871

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of copper(I) acetate with Se(SiMe3)2 in the presence of tertiary phosphanes leads to the formation of clusters 1 and 2. The crystal structures of these two clusters show that the CuSe frameworks are isomers, whose structures differ considerably as a result of different ligand shells. The Se22 framework of 2 is shown on the right. (Formula Presented.) (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2287 / 2289

页数：3

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