CONTROL OF PRODUCT SELECTIVITY FOR THE EPOXIDATION OF ALLYL ALCOHOL BY VARIATION OF THE ACIDITY OF THE CATALYST TS-1

被引：44
作者：
HUTCHINGS, GJ
LEE, DF
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 09期
关键词：
D O I：
10.1039/c39940001095
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The acidity of TS-1 controls the product selectivity for the epoxidation of allyl alcohol with H2O2; base treatment of TS-l enhances the selectivity to glycidol whereas incorporation of Bronsted acid sites enhances the selectivity to the products of solvolysis ring opening reactions.
引用
收藏
页码：1095 / 1096
页数：2
相关论文
共 10 条
[1]   EPOXIDATION OF LOWER OLEFINS WITH HYDROGEN-PEROXIDE AND TITANIUM SILICALITE [J].
CLERICI, MG ;
INGALLINA, P .
JOURNAL OF CATALYSIS, 1993, 140 (01) :71-83
[2]  
CLERICI MG, 1984, Patent No. 100625
[3]  
ESPOSITO A, 1985, Patent No. 2116974
[4]  
ESPOSITO A, 1985, Patent No. 2116974
[5]  
GOSSER LW, 1987, Patent No. 4681751
[6]   AL-27 AND SI-29 NMR-STUDIES OF HZSM-5 .1. THE EFFECT OF SORBED MOLECULES [J].
MEINHOLD, RH ;
BIBBY, DM .
ZEOLITES, 1990, 10 (02) :74-84
[7]  
NERI C, 1984, Patent No. 100119
[8]  
Taramasso M., 1983, US Pat, Patent No. [4410501, US4410501]
[9]   HYDROXYLATION OF BENZENE AND HEXANE BY OXYGEN AND HYDROGEN OVER PALLADIUM-CONTAINING TITANIUM SILICALITES [J].
TATSUMI, T ;
YUASA, K ;
TOMINAGA, H .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (19) :1446-1447
[10]   EVIDENCE FOR THE SIMULTANEOUS INCORPORATION OF AL AND TI IN MFI STRUCTURE (AL-TS-1) [J].
THANGARAJ, A ;
KUMAR, R ;
SIVASANKER, S .
ZEOLITES, 1992, 12 (02) :135-137
1