NMR-STUDY OF ONE-DIMENSIONAL IONIC CONDUCTOR WITH HOLLANDITE-TYPE STRUCTURE .2. FREQUENCY-DEPENDENCE OF SPIN-LATTICE RELAXATION-TIME OF AL-27

被引:10
作者
ONODA, Y
FUJIKI, Y
TAKIGAWA, M
YASUOKA, H
YOSHIKADO, S
OHACHI, T
TANIGUCHI, I
机构
[1] UNIV TOKYO,INST SOLID STATE PHYS,MINATO KU,TOKYO 106,JAPAN
[2] DOSHISHA UNIV,DEPT ELECTR,KYOTO 602,JAPAN
关键词
DIFFUSION - Mathematical Models - IONS - Diffusion - POTASSIUM COMPOUNDS - Electric Conductivity - SPECTROMETERS; MAGNETIC RESONANCE - Applications;
D O I
10.1016/0167-2738(85)90060-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Frequency dependence of spin-lattice relaxation time T//1 of **2**7Al in one-dimensional K** plus ion conductor, K-Al-priderite, was measured at 45 K in the frequency range from 10. 1 MHz to 55 MHz. It is found that T//1 agrees well with the continuum diffusion model. The intrinsic activation energy is determined to be 0. 058 ev. It was concluded that the introduction of the two barrier model which assumes the existance of two different barriers, the intrinsic barrier and the impurity barrier, is necessary to explain the temperature dependence of T//1.
引用
收藏
页码:127 / 131
页数:5
相关论文
共 18 条
[1]   ANOMALOUS FREQUENCY-DEPENDENT CONDUCTIVITY IN DISORDERED ONE-DIMENSIONAL SYSTEMS [J].
BERNASCONI, J ;
BEYELER, HU ;
STRASSLER, S .
PHYSICAL REVIEW LETTERS, 1979, 42 (13) :819-822
[2]   DIFFUSION AND HOPPING CONDUCTIVITY IN DISORDERED ONE-DIMENSIONAL LATTICE SYSTEMS [J].
BERNASCONI, J ;
SCHNEIDER, WR ;
WYSS, W .
ZEITSCHRIFT FUR PHYSIK B-CONDENSED MATTER, 1980, 37 (02) :175-184
[3]  
Beyeler H. U., 1979, Fast ion transport in solids. Electrodes and electrolytes, P503
[4]  
Beyeler H. U., 1979, Physics of Superionic Conductors, P77
[5]  
BEYELER HU, 1980, PHYS REV B, V22, P2988, DOI 10.1103/PhysRevB.22.2988
[6]  
Bjorkstam J. L., 1980, Magnetic Resonance Review, V6, P1
[7]  
Fujiki Y., 1983, J JPN ASS MIN PET EC, V78, P109
[8]  
HELD G, 1975, 18 P C AMP, P461
[9]   DEFECT DIFFUSION-MODELS IN NMR AND DIELECTRIC-RELAXATION [J].
KIMMICH, R ;
VOIGT, G .
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 1978, 33 (11) :1294-1306
[10]   NMR-STUDY OF ONE-DIMENSIONAL IONIC CONDUCTORS WITH HOLLANDITE-TYPE STRUCTURE [J].
ONODA, Y ;
FUJIKI, Y ;
YOSHIKADO, S ;
OHACHI, T ;
TANIGUCHI, I .
SOLID STATE IONICS, 1983, 9-10 (DEC) :1311-1315