PHOTOCHEMICAL ISOMERIZATION OF DIHALOMETHANES IN ARGON MATRICES

被引：117

作者：

MAIER, G ^{[1
]}

REISENAUER, HP ^{[1
]}

HU, J ^{[1
]}

SCHAAD, LJ ^{[1
]}

HESS, BA ^{[1
]}

机构：

[1] VANDERBILT UNIV,DEPT CHEM,NASHVILLE,TN 37235

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1990年 / 112卷 / 13期

关键词：

D O I：

10.1021/ja00169a020

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It was found that photolysis of various dihalomethanes in an argon matrix at 12 K gives rise to isomeric species. Ab initio calculations indicate that in these isomers one halogen has been removed from the carbon and forms a weak bond with the other halogen on the carbon. This is supported by comparison of the observed IR spectra of the photoisomers with those calculated by ab initio methods. © 1990, American Chemical Society. All rights reserved.

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页码：5117 / 5122

页数：6

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