THERMOCATALYTIC HYDROCONVERSION OF HEAVY PETROLEUM CUTS WITH DISPERSED CATALYST

被引:70
作者
DELBIANCO, A
PANARITI, N
DICARLO, S
ELMOUCHNINO, J
FIXARI, B
LEPERCHEC, P
机构
[1] LAB MAT ORGAN,CNRS,BP 24,F-69390 VERNAISON,FRANCE
[2] ENIRICERCHE SPA,MILAN,ITALY
[3] EURON SPA,MILAN,ITALY
关键词
DISPERSED CATALYST; HEAVY-OIL; HYDROCONVERSION; METAL SALTS; ORGANOMETALLIC; PETROLEUM;
D O I
10.1016/0926-860X(93)80041-N
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This report concerns the use of unsupported dispersed catalysts in upgrading heavy feeds. The conversion of heavy crudes and resids into valuable products requires an efficient hydrogen activation. A method recently investigated deals with the use of metallic or organometallic (water- or oil-soluble) compounds, which under a thermal treatment decompose and give rise to a slurry of fine solid particles. This active form of catalyst promotes locally the spill-over of the hydrogen and therefore enhances the conversion of resids to distillate, reducing the coke formation. The primary objective of this report is to assess the current state of knowledge on this field, in order to identify new directions and strategies for Research.
引用
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页码:1 / 16
页数:16
相关论文
共 107 条
  • [61] HOWELL JA, 1985, Patent No. 183269
  • [62] HOWELL JA, 1987, Patent No. 4708784
  • [63] KIM H, 1989, PREPR PAP AM CHEM SO, V34, P1431
  • [64] KIM H, 1989, AM CHEM SOC PREP DIV, V34, P1446
  • [65] INTERACTIVE CHEMISTRY OF COAL OIL REACTIONS USING MODEL SYSTEMS
    KIM, HG
    CURTIS, CW
    [J]. ENERGY & FUELS, 1990, 4 (02) : 214 - 219
  • [66] REACTION PATHWAYS OF MODEL COPROCESSING SYSTEMS USING MOLYBDENUM NAPHTHENATE AND EXCESS SULFUR
    KIM, HG
    CURTIS, CW
    [J]. ENERGY & FUELS, 1990, 4 (02) : 206 - 214
  • [67] KRASTMAN D, 1990, A CHEM SOC DIV FUEL, V35, P570
  • [68] KUKES SG, 1984, Patent No. 142033
  • [69] KUSHIYAMA S, 1989, IND ENG CHEM RES, V30, P881
  • [70] LANG RJ, 1989, Patent No. 4831003