COBALT SCHIFF-BASE COMPLEX CATALYZED DEHYDROGENATION OF AMINES WITH TERT-BUTYL HYDROPEROXIDE

被引：26

作者：

MARUYAMA, K

KUSUKAWA, T

HIGUCHI, Y

NISHINAGA, A

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 07期

关键词：

D O I：

10.1246/cl.1991.1093

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cobalt Schiff base complex catalyzed oxidation of secondary aromatic amines with t-butyl hydroperoxide resulted selectively in dehydrogenation to give the corresponding imines. Proposed mechanism involves electron transfer from the nitrogen atom in the substrate to t-butyloxyl or t-butylperoxyl radical produced in situ from a t-butylperoxocobalt(III) complex intermediate.

引用

页码：1093 / 1096

页数：4

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