TRIAZINE-BASED POLYMERS .1. SYNTHESIS OF POLY[(2,4-DICHLORO-6-ETHOXY-S-TRIAZINE)-ALT-(BISPHENOL-A)]

被引:13
作者
BRAUN, D
ZISER, T
机构
[1] Deutsches Kunststoff-Institut, Darmstadt, D-64289
来源
ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1994年 / 219卷
关键词
D O I
10.1002/apmc.1994.052190103
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Poly[(2,4-dichloro-6-ethoxy-s-triazine)-alt-(bisphenol A)] (T-BPA), a polymer with interesting mechanical and thermal properties, was synthesized by phase transfer catalysed interfacial polycondensation. The reaction conditions for the synthesis of T-BPA were investigated and optimized. The influence of several reaction parameters, such as temperature, reaction time, type and concentration of phase transfer catalyst, concentration of monomers, type of solvent, type of base, salt addition, and molecular weight terminator concentration on the reduced specific viscosity and yield of T-BPA was investigated. As a result, it is possible to synthesize T-BPA at reaction conditions being favourable with regard to the costs of energy and equipment.
引用
收藏
页码:27 / 42
页数:16
相关论文
共 18 条
  • [1] PREPARATION AND PROPERTIES OF POLY(2-CHLOROCYANURATE) OF BISPHENOL-A
    ALLEN, G
    DEBOOS, AG
    [J]. POLYMER, 1974, 15 (01) : 56 - 59
  • [2] [Anonymous], 1977, PHASE TRANSFER CATAL
  • [3] AUDEBERT R, 1970, B SOC CHIM FR B, V2, P606
  • [4] INTERFACIAL SYNTHESIS .1. PHASE-TRANSFER CATALYZED SYNTHESIS OF POLYHYDROXY ETHER
    BANTHIA, AK
    LUNSFORD, D
    WEBSTER, DC
    MCGRATH, JE
    [J]. JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1981, A15 (05): : 943 - 966
  • [5] BRAUN D, UNPUB ANGEW MAKROMOL
  • [6] POLYCYANURATES FROM 2-ALKOXY-4,6-DICHLORO-S-TRIAZINES AND 2,2-BIS(P-HYDROXYPHENYL)PROPANE
    BREED, LW
    ELLIOTT, RL
    [J]. JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1969, 7 (9PA1): : 2749 - &
  • [7] Dehmlow E. V., 1983, PHASE TRANSFER CATAL
  • [8] SYNTHESES OF SOME CONDENSATION POLYMERS BY PHASE-TRANSFER CATALYZED POLYCONDENSATION
    IMAI, Y
    [J]. JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1981, A15 (05): : 833 - 852
  • [9] ISMAIL RM, 1972, ANGEW MAKROMOL CHEM, V21, P25
  • [10] MORGAN PW, 1965, CONDENSATION POLYM I, P80