MONO N-ALKYLATION AND N-ACYLATION OF CYCLEN AND CYCLAM VIA THEIR METALTRICARBONYL COMPLEXES (M=CR, MO)

被引：43

作者：

PATINEC, V ^{[1
]}

YAOUANC, JJ ^{[1
]}

CLEMENT, JC ^{[1
]}

HANDEL, H ^{[1
]}

DESABBAYES, H ^{[1
]}

机构：

[1] FAC SCI & TECH BREST,CNRS,CHIM ELECTROCHIM MOLEC & CHIM ANALYT LAB,F-29200 BREST,FRANCE

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 01期

关键词：

D O I：

10.1016/0040-4039(94)02157-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of metaltricarbonyl complexes of cyclen and cyclam with enolisable aldehydes or acid chlorides yields, after removal of the protecting M(CO)(3) moiety, selectively mono N-functionalized derivatives.

引用

页码：79 / 82

页数：4

共 22 条

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