AN APPROACH OF THE STRUCTURE OF ICOSAHEDRAL AL6CULI3 BY MULTIPLE TWINNING OF A RHOMBOHEDRAL CRYSTAL

被引:24
作者
AUDIER, M
GUYOT, P
机构
[1] ENSEEG, France
来源
ACTA METALLURGICA | 1988年 / 36卷 / 05期
关键词
Aluminum Compounds - Copper Compounds - Crystallography - Crystals--Structure - Lithium Compounds;
D O I
10.1016/0001-6160(88)90284-2
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
An analysis of the macroscopic morphology of slowly solidified Al6CuLi3 icosahedral quasicrystals, based on a multiple-twinning of a rhombohedral crystal nucleated on a 20 branded-star seed, is proposed. Consideration of dendrite growth by accretion of polyatomic clusters with icosahedral symmetry gives the key of the R3¯m twinned crystal structure. Its Fourier transform displays a pseudoicosahedral symmetry, with deviations from the perfect one in agreement with certain features of electron and X-rays diffraction patterns experimentally observed, as periodicities, symmetry dependent distortions and splitting of Bragg reflexions.
引用
收藏
页码:1321 / 1328
页数:8
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