MULTIPLE-SCATTERING CALCULATIONS ON A SERIES OF M(H2O)(6)(2+) COMPLEXES WITH M=V TO CU

被引：13
|
作者：
BRIOIS, V
LAGARDE, P
BROUDER, C
SAINCTAVIT, P
VERDAGUER, M
机构：
[1] LPS, F-54596 VANDOEUVRE LES NANCY, FRANCE
[2] LMCP, UA09, F-75252 PARIS 05, FRANCE
[3] LCMT, F-75252 PARIS 05, FRANCE
来源：
PHYSICA B | 1995年 / 208卷 / 1-4期
关键词：
D O I：
10.1016/0921-4526(94)00632-6
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
The metal K-edge X-ray absorption spectra of a series of M (H2O)(6)(2+) complexes with M = V to Cu have been recorded in aqueous solution. After the white line, all spectra are characterized by a structure whose intensity depends on the absorbing metal. From multiple-scattering (MS) calculations, it has been shown that this structure is due to the collinear MS paths M --> O --> M --> O --> M. The influence of the metal is understood by the analysis of the p phase shifts of the scatterers.
引用
收藏
页码：51 / 52
页数：2
相关论文
共 50 条
  • [41] Synthesis, Crystal Structure and Electrochemical Property of the Complex [Cu(m-NBA)(2,2′-bipy)(H2O)2]•m-NBA•H2O
    Chen Zhi-Min
    Zhang Fu-Xing
    Zeng Rong-Ying
    Kuang Dai-Zhi
    Feng Yong-Lan
    Wang Jian-Qiu
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2009, 25 (03) : 548 - 551
  • [42] Hexachloroplatinates of the Lanthanides:: Syntheses and thermal decomposition of [M(NO3)2(H2O)6]2[PtC16] • 2H2O (M = La, Pr) and [M(NO3)(H2O)7][PtCl6] • 4H2O (M = Gd, Dy)
    Arndt, Annika
    Posavec, Damir
    Schwarzer, Stefan
    Wickleder, Mathias S.
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2008, 634 (03): : 431 - 435
  • [43] Formation of [CoCl4(H2O)2]2- complex in CoCl2•MgCl2•8H2O double salt:: structural and energetic properties of [MCl4(H2O)2]2- and [M(H2O)6]2+ (M = Mg, Co)
    Waizumi, K
    Matsumoto, T
    Abe, T
    Fukushima, N
    Masuda, H
    JOURNAL OF SOLID STATE CHEMISTRY, 2003, 174 (01) : 182 - 188
  • [44] THEORETICAL CALCULATIONS OF THE JAHN-TELLER EFFECT IN THE HEXAHYDRATED COPPER(II), CHROMIUM(II), AND MANGANESE(III) IONS, [CU(H2O)6]2+, [CR(H2O)6]2+, AND [MN(H2O)6]3+, AND COMPARISONS WITH THE HEXAHYDRATED COPPER(I), CHROMIUM(III), AND MANGANESE(II) CLUSTERS
    AKESSON, R
    PETTERSSON, LGM
    SANDSTROM, M
    WAHLGREN, U
    JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (01): : 150 - 156
  • [45] [M(dipicH2)(H2O)3]2+ M = Ni, Cu, Zn (dipicH2 = dipicolinic acid) -: A combined crystallographic, spectroscopic and computational study
    Prasad, T. K.
    Rajasekharan, M. V.
    POLYHEDRON, 2007, 26 (07) : 1364 - 1372
  • [46] EPR investigation of local structure for the [Mn(H2O)6]2+ cluster in M(ClO4)2 • 6H2O:Mn2+ (M = Cd, Hg) systems at different temperatures
    Li, Ju-Fen
    Kuang, Xiao-Yu
    Tang, Bin
    Luo, Qiang
    EUROPEAN PHYSICAL JOURNAL-APPLIED PHYSICS, 2015, 71 (03):
  • [47] 3D hydrogen bonded metal-organic frameworks constructed from [M(H2O)6][M′(dipicolinate)2] • mH2O (M/M′ = Zn/Ni or Ni/Ni).: Identification of intercalated acyclic (H2O)6/(H2O)10 clusters
    Kirillova, Marina V.
    Kirillov, Alexander M.
    da Silva, M. Fatima C. Guedes
    Kopylovich, Maximilian N.
    da Silva, Joao J. R. Frausto
    Pombeiro, Armando J. L.
    INORGANICA CHIMICA ACTA, 2008, 361 (06) : 1728 - 1737
  • [48] The conditions of formation of heterometallic complexes in the GeCl4 (SnCl4)-citric acid-M(CH3COO)2-H2O systems. The crystal and molecular structures of [M(H2O)6][Ge(HCit)2] · 4H2O (M = Mg, Mn, Co, Cu, Zn) and [M(H2O)6][Sn(HCit)2] · 4H2O (M = Mg, Co, Ni)
    E. E. Martsinko
    L. Kh. Minacheva
    E. A. Chebanenko
    I. I. Seifullina
    V. S. Sergienko
    A. V. Churakov
    Russian Journal of Inorganic Chemistry, 2013, 58 : 515 - 522
  • [49] The conditions of formation of heterometallic complexes in the GeCl4 (SnCl4)-citric acid-M(CH3COO)2-H2O systems. The crystal and molecular structures of [M(H2O)6][Ge(HCit)2] • 4H2O (M = Mg, Mn, Co, Cu, Zn) and [M(H2O)6][Sn(HCit)2] • 4H2O (M = Mg, Co, Ni)
    Martsinko, E. E.
    Minacheva, L. Kh.
    Chebanenko, E. A.
    Seifullina, I. I.
    Sergienko, V. S.
    Churakov, A. V.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 58 (05) : 515 - 522
  • [50] Influence of Vibration Changes on Jahn-Teller Distortion in [Fe(H2O)6]2+ and [Fe(NO)(H2O)5]2+
    Sun, H. T.
    Li, Y. M.
    Wang, Z. Z.
    Su, C. F.
    Zhou, Z. Y.
    Tang, K.
    POLISH JOURNAL OF CHEMISTRY, 2009, 83 (02) : 303 - 313
12345