MULTIPLE-SCATTERING CALCULATIONS ON A SERIES OF M(H2O)(6)(2+) COMPLEXES WITH M=V TO CU

被引：13

作者：

BRIOIS, V

LAGARDE, P

BROUDER, C

SAINCTAVIT, P

VERDAGUER, M

机构：

[1] LPS, F-54596 VANDOEUVRE LES NANCY, FRANCE

[2] LMCP, UA09, F-75252 PARIS 05, FRANCE

[3] LCMT, F-75252 PARIS 05, FRANCE

来源：

PHYSICA B | 1995年 / 208卷 / 1-4期

关键词：

D O I：

10.1016/0921-4526(94)00632-6

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

The metal K-edge X-ray absorption spectra of a series of M (H2O)(6)(2+) complexes with M = V to Cu have been recorded in aqueous solution. After the white line, all spectra are characterized by a structure whose intensity depends on the absorbing metal. From multiple-scattering (MS) calculations, it has been shown that this structure is due to the collinear MS paths M --> O --> M --> O --> M. The influence of the metal is understood by the analysis of the p phase shifts of the scatterers.

引用

页码：51 / 52

页数：2

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