A NEW MECHANISM FOR THE REARRANGEMENT OF THE ICOSAHEDRAL CARBORANES

被引：7

作者：

JOHNSON, BFG

ROBERTS, YV

PARISINI, E

机构：

[1] Department of Chemistry, University of Edinburgh, Edinburgh, EH9 3JJ, West Mains Road

来源：

INORGANICA CHIMICA ACTA | 1993年 / 211卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)82837-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new mechanism which involves the anticubeoctahedron as the complementary geometry is postulated to rationalise previously reported data on the rearrangement of various icosahedral carboranes.

引用

页码：17 / 21

页数：5

共 12 条

[1] THERMAL-ISOMERIZATION OF REGIOSPECIFICALLY B-10-LABELED ICOSAHEDRAL CARBORANES [J].

EDVENSON, GM ;

GAINES, DF .

INORGANIC CHEMISTRY, 1990, 29 (06) :1210-1216

[2] A NEW APPROACH TO THE STRUCTURES AND REARRANGEMENTS IN CLOSO-BORON HYDRIDES [J].

FULLER, DJ ;

KEPERT, DL .

INORGANIC CHEMISTRY, 1982, 21 (01) :163-167

[3] THERMAL REARRANGEMENTS OF ICOSAHEDRAL CARBORANES - MOLECULAR AND CRYSTAL-STRUCTURE OF 5,12-DICHLORO-1,7-DIMETHYL-1,7-DICARBA-CLOSO-DODECABORANE(12) [J].

HART, HV ;

LIPSCOMB, WN .

INORGANIC CHEMISTRY, 1973, 12 (11) :2644-2649

[4]

JOHNSN BFG, 1988, J CHEM SOC CHEM COMM, P889

[5] NATURE OF [FE3(CO)12] IN SOLUTION [J].

JOHNSON, BFG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1976, (17) :703-704

[6] DYNAMIC PROCESSES OF TRINUCLEAR CARBONYL CLUSTERS [FE-3(CO)12], [RU-3(CO)12], [OS-3(CO)12] AND THEIR DERIVATIVES [J].

JOHNSON, BFG ;

BOTT, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (08) :2437-2444

[7]

KAESZ HD, 1967, J AM CHEM SOC, V86, P4218

[8] FRAMEWORK REARRANGEMENT IN BORANES AND CARBORANES [J].

LIPSCOMB, WN .

SCIENCE, 1966, 153 (3734) :373-&

[9]

Muetterties E. L., 1968, POLYHEDRAL BORANES, P70

[10]

Muetterties E. L., 1975, BORON HYDRIDE CHEM

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