EXPERIMENTAL AND THEORETICAL-STUDY OF THE REACTIVITY OF CLUSTER-BOUND DICARBON - SYNTHESIS AND STRUCTURES OF NOVEL ELECTRON-RICH RU5 CLUSTERS

被引：26

作者：

ADAMS, CJ

BRUCE, MI

LIDDELL, MJ

SKELTON, BW

WHITE, AH

机构：

[1] UNIV STRASBOURG 1,CHIM QUANT LAB,F-67070 STRASBOURG,FRANCE

[2] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6009,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 18期

关键词：

D O I：

10.1039/c39920001314

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An EHMO (extended Huckel molecular orbital) study of [Ru5(mu5-C2)(mu-SH)2(mu-PH2)2(CO)11] suggests that C(beta) should behave as a nucleophile; this is found experimentally in the reactions of the SMe-PPh2 derivative with H-2 or C2H4, in which C(beta) inserts into H-H or C-H bonds to give mu3-CCHR ligands (R = H or CH=CH2, respectively), as shown by X-ray structure determinations carried out on [Ru5(mu3-CCHR)(mu3-SMe)2(mu-PPh2)2(CO)10] (R=H and CH=CH2).

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页码：1314 / 1318

页数：5

相关论文

共 20 条

[1] SYNTHESIS AND X-RAY STRUCTURES OF 2 COMPLEXES CONTAINING DICARBON (C2) ATTACHED TO RU5 CLUSTERS WITH UNUSUAL CORE GEOMETRIES [J].

ADAMS, CJ ;

BRUCE, MI ;

SKELTON, BW ;

WHITE, AH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (01) :26-29

[2] SYNTHESIS AND STRUCTURE OF [ASPH4][RU6H(MU-O=CNME2)2(MU-CO)4-(CO)14].ME2C=O - A CYCLIC HYDRIDO-HEXAMETALLIC ANION [J].

BOAG, NM ;

KNOBLER, CB ;

KAESZ, HD .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1983, 22 (03) :249-250

[3]

BOAG NM, 1983, ANGEW CHEM S, P198

[4]

BOAG NM, 1983, ANGEW CHEM, V95, P243

[5] THE CLUSTER ANION [RU6H(CO)15S3]- - A PLANAR HEXANUCLEAR METAL FRAMEWORK WITH ALMOST PERFECT C3V SYMMETRY [J].

BODENSIECK, U ;

STOECKLIEVANS, H ;

SUSSFINK, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (09) :1126-1127

[6]

BODENSIECK U, 1991, ANGEW CHEM, V103, P1147

[7] ORGANOMETALLIC CHEMISTRY OF VINYLIDENE AND RELATED UNSATURATED CARBENES [J].

BRUCE, MI .

CHEMICAL REVIEWS, 1991, 91 (02) :197-257

[8] THE 1ST EXAMPLE OF A MU-4-ETA-1,ETA-2-ACETYLIDE DIANION - PREPARATION AND X-RAY STRUCTURE OF RU4(MU-4-ETA-1,ETA-2-C2)(MU-PPH2)2(CO)12 [J].

BRUCE, MI ;

SNOW, MR ;

TIEKINK, ERT ;

WILLIAMS, ML .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (09) :701-702

[9] CLUSTER CHEMISTRY .32. SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [RU5(MU-5-ETA-2-C2PPH2-P)(MU-PPH2)(CO)13], A COMPLEX CONTAINING AN ALKYNYL LIGAND IN EXTENDED INTERACTION WITH AN OPEN RU5 CLUSTER [J].

BRUCE, MI ;

WILLIAMS, ML ;

PATRICK, JM ;

WHITE, AH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (06) :1229-1234

[10] STRUCTURAL VERSATILITY OF RU-4 BUTTERFLIES - THE MOLECULAR-STRUCTURES OF RU4(CO)13(MU-PPH2)(MU-ETA-2-C=C-T-BU) AND RU4(CO)8(MU-PPH2)2(MU-ETA-2-C=C-T-BU)(MU-3-ETA-2-C=C-T-BU)(PH2PC=C-T-BU).1/2C6H14 - CLUSTERS WITH ALMOST PLANAR METAL FRAMEWORKS [J].

CARTY, AJ ;

MACLAUGHLIN, SA ;

VANWAGNER, J ;

TAYLOR, NJ .

ORGANOMETALLICS, 1982, 1 (07) :1013-1015