Investigation and Discrimination of Ballpoint Pen Inks by Analytical Techniques and Chemometrics

被引:0
|
作者
Sharif, Mehwish [1 ]
Chand, Sohail [2 ]
Tirmazi, Syed Azhar Ali Shah [1 ]
Farooq, Umar [1 ]
Athar, Muhammad Makshoof [1 ]
Batool, Madeeha [1 ]
机构
[1] Univ Punjab, Sch Chem, Lahore 54590, Pakistan
[2] Univ Punjab, Coll Stat & Actuarial Sci, Lahore 54590, Pakistan
关键词
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A population study has been performed for Pakistani ballpoint pen inks of blue, black, red, and green colors (a total of four colors) commercially used in Pakistan. Ballpoint pen inks have been investigated and discriminated by using UV/Vis spectroscopy and FTIR spectroscopy. We have calculated and compared the results in terms of discriminating power (DP). The statistical techniques of principal component analysis and cluster analysis have been applied on obtained data. By visual comparison, the best DP is obtained for green ballpoint pen inks, i.e., 0.866 by using UV/Vis spectroscopy and FTIR techniques. Black and red ballpoint pen inks showed the highest DPs by using UV/Vis spectroscopy; however, blue ballpoint pen inks got the highest DP by using FTIR spectroscopy. DP has been improved by using chemometric techniques and higher DPs are obtained as compared to visual examination.
引用
收藏
页数:13
相关论文
共 50 条
  • [41] Characterization of ballpoint pen inks by thermal desorption and gas chromatography-mass spectrometry
    Bügler, JH
    Buchner, H
    Dallmayer, A
    JOURNAL OF FORENSIC SCIENCES, 2005, 50 (05) : 1209 - 1214
  • [42] Nondestructive classification and identification of ballpoint pen inks by Raman spectroscopy for forensic document examinations
    Lee, Loong Chuen
    Ab Samad, Muhammad Ismail
    Ismail, Mohamad Azlan Mohd
    JOURNAL OF ANALYTICAL CHEMISTRY, 2016, 71 (07) : 723 - 729
  • [43] Analysis of ballpoint pen inks' handwriting for the forensic differentiation with high performance liquid chromatography
    Li, XQ
    Wang, YJ
    Shi, XF
    Xu, YJ
    Wang, JH
    CHINESE JOURNAL OF ANALYTICAL CHEMISTRY, 2004, 32 (05) : 657 - 660
  • [44] Determination of writing age of blue ballpoint pen inks by high performance liquid chromatography
    Shi, Xiao-fan
    Li, Xin-qian
    Xu, Ying-jian
    Wang, Jing-han
    Wang, Yan-ji
    SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26 (09) : 1765 - 1768
  • [45] Differentiation of blue ballpoint pen inks by positive and negative mode LDI-MS
    Gallidabino, M.
    Weyermann, C.
    Marquis, R.
    FORENSIC SCIENCE INTERNATIONAL, 2011, 204 (1-3) : 169 - 178
  • [46] Nondestructive classification and identification of ballpoint pen inks by Raman spectroscopy for forensic document examinations
    Loong Chuen Lee
    Muhammad Ismail Ab Samad
    Mohamad Azlan Mohd Ismail
    Journal of Analytical Chemistry, 2016, 71 : 723 - 729
  • [47] Forensic Identification of Dyes in Ballpoint Pen Inks Using LC-ESI-MS
    Akhmerova, Dilara
    Krylova, Alina
    Stavrianidi, Andrey
    Shpigun, Oleg
    Rodin, Igor
    CHROMATOGRAPHIA, 2017, 80 (11) : 1701 - 1709
  • [48] Dating The Ballpoint Pen Inks Using Gas Chromatography-Mass Spectrometry Technique
    El-Sabbah, M. M. B.
    Gomaa, A. Z.
    El-Hefny, D. E.
    Al-Hawary, A. S.
    EGYPTIAN JOURNAL OF CHEMISTRY, 2019, 62 (03): : 385 - 400
  • [49] Classification of ballpoint pen inks based on selective extraction and subsequent digital color and cluster analyses
    Kalinichev, Andrey, V
    Kravchenko, Anastasia, V
    Gryazev, Ivan P.
    Kechin, Arseniy A.
    Karpukhin, Oleg R.
    Khairullina, Evgeniia M.
    Kartsova, Liudmila A.
    Golovkina, Anna G.
    Kozynchenko, Vladimir A.
    Peshkova, Maria A.
    Tumkin, Ilya I.
    ANALYST, 2022, 147 (13) : 3055 - 3064
  • [50] Ballpoint pen inks: Characterization by positive and negative ion-electrospray ionization mass spectrometry for the forensic examination of writing inks
    Ng, LK
    Lafontaine, P
    Brazeau, L
    JOURNAL OF FORENSIC SCIENCES, 2002, 47 (06) : 1238 - 1247