EXCESS THERMODYNAMIC PROPERTIES OF MIXTURES OF ALKYL BENZOATES WITH N-HEPTANE

被引:3
|
作者
BLANCO, AM
ORTEGA, J
机构
[1] Laboratorio de Termodinámica y Fisicoquimica, Escuela Superior de Ingenieros Industriales, Universidad de Las Palmas de Gran Canaria, Las Palmas de Gran Canaria
关键词
BINARY MIXTURES; N-HEPTANE; METHYL ESTERS; THERMODYNAMIC PROPERTIES; VISCOSITY;
D O I
10.1007/BF01563794
中图分类号
O414.1 [热力学];
学科分类号
摘要
The paper reports h(E) values at 298.15 K and upsilon(E) and deltaeta values at various temperatures for binary mixtures of propyl or butyl benzoate and n-heptane. The excess Gibbs energy of viscous flow, DELTAg*E, and the thermodynamic activation properties were calculated from these values. The results are compared with those for similar mixtures and interpreted on the basis of the characteristic dipole-dipole interactions of alkyl esters.
引用
收藏
页码:699 / 710
页数:12
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