PREPARATION OF 2-AZIDO-4-O-BENZOYL-2,6-DIDEOXY-3-O-METHYL-BETA-D-ALLOPYRANOSE AND ITS DISACCHARIDE DERIVATIVE

被引：1

作者：

WANG, F ^{[1
]}

SAKAIRI, N ^{[1
]}

KUZUHARA, H ^{[1
]}

机构：

[1] INST PHYS & CHEM RES,WAKO,SAITAMA 35101,JAPAN

来源：

JOURNAL OF CARBOHYDRATE CHEMISTRY | 1993年 / 12卷 / 07期

关键词：

D O I：

10.1080/07328309308020097

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

2-Azido-4-O-benzoyl-2,6-dideoxy-3-O-methyl-D-allopyranose, needed as one of the building blocks for construction of a novel cyclodextrin-like compound, was prepared in the form of crystalline beta-anomer 6 from methyl 2-azido-4,6-O-benzylidene-2-deoxy-alpha-D-allopyranoside 1. As a model of alpha-glycosidation necessary for formation of a cyclic structure, 6 was converted into the corresponding beta-glycosyl trichloroacetimidate and coupled with methyl 6-O-benzyl-2,3-di-O-methyl-alpha-D-glucopyranoside 8, giving alpha(1-->4)-linked disaccharide derivative 9.

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页码：823 / 831

页数：9

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