ELECTROKINETIC REMEDIATION .1. MODELING OF SIMPLE SYSTEMS

被引:17
作者
WILSON, DJ [1 ]
RODRIGUEZMAROTO, JM [1 ]
GOMEZLAHOZ, C [1 ]
机构
[1] UNIV MALAGA,FAC CIENCIAS,DEPT INGN QUIM,E-29071 MALAGA,SPAIN
关键词
D O I
10.1080/01496399508013121
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A one-dimensional model is developed for simulating the electrokinetic treatment of saturated porous media contaminated with an ionic salt. Simulations of simple, unenhanced electrokinetic treatment for the removal of a nonamphoteric salt such as cadmium sulfate exhibit a severe drop-off in electric current and in remediation rate after about 50-60% of the cation has been removed. Simulation of electrokinetic treatment in which the OH- generated in the cathode compartment is partially neutralized by the addition of acid show rapid and complete removal of the cation. Partial neutralization of H+ in the anode compartment by addition of base results in immobilization of the toxic metal as the solid hydroxide, although this should be a useful technique for the removal of arsenate and selenate.
引用
收藏
页码:2937 / 2961
页数:25
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