ELECTROCHEMICAL SYNTHESIS AND CRYSTAL-STRUCTURE OF A NOVEL ONE-DIMENSIONAL HALOGEN-BRIDGED NICKEL(III) COMPLEX

被引：2
|
作者：
OZAWA, Y
TORIUMI, K
机构：
来源：
CHEMISTRY LETTERS | 1995年 / 04期
关键词：
D O I：
10.1246/cl.1995.257
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel halogen-bridged one-dimensional Ni-III-X-Ni-III compound, {[Ni-III(en)(2)Cl]Cl-2}infinity) (en = C2H8N2) has been synthesized by electrochemical oxidation. Single crystal X-ray crystallography revealed that a bridging halogen ion is located on the midpoint between two Ni(III) atoms with Ni-Cl 2.438 (1) Angstrom. This is the first example for electrocrystallization of halogen-bridged 1-D metal complexes.
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页码：257 / 258
页数：2
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