SYNTHESIS AND CHARACTERIZATION OF CIS-(2,2'-BIPYRIDINE)(2,2'-BIQUINOLINE)DICHLORORUTHENIUM(II) AND ITS COORDINATION CHEMISTRY WITH IMIDAZOLE DERIVATIVES

被引：23

作者：

HEIJDEN, M ^{[1
]}

VANVLIET, PM ^{[1
]}

HAASNOOT, JG ^{[1
]}

REEDIJK, J ^{[1
]}

机构：

[1] LEIDEN UNIV,LEIDEN INST CHEM,GORLAEUS LABS,POB 9502,2300 RA LEIDEN,NETHERLANDS

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 24期

关键词：

D O I：

10.1039/dt9930003675

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of cis-[Ru(bipy)(bquin)Cl2] (bipy = 2,2'-bipyridine, bquin = 2,2'-biquinoline) with several imidazole derivatives have been studied. Substitution of only one chloride ligand takes place exclusively trans to bquin, resulting in the synthesis of cis- [Ru(bipy)(bquin)(L)Cl]PF6 (L = Him, 1-mim or 5-mim; Him = imidazole, 1-mim = 1-methylimidazole, 5-mim = 5-methylimidazole). This substitution preference for imidazoles indicates that bquin has a stronger electronic trans influence than bipy, and that the steric effects of bquin do not appear to obstruct the approach of a substituting ligand. By substitution of the second chloride the compounds cis-[Ru(bipy)(bquin)L2][PF6]2 and cis-[Ru(bipy)(bquin)(1-mim)-(HIM)][PF6]2 were isolated. The properties of the compounds have been studied by H-1 NMR spectroscopy and electrochemistry. The studies show that cis-[Ru(bipy)(bquin)Cl2] incorporates potential covalent binding properties for biomolecules like histidine and DNA.

引用

页码：3675 / 3679

页数：5

共 50 条

[41] Synthesis and characterization of ruthenium(II) bis(2,2 prime -bipyridine)-containing polyamines [J].

Carraher, C.E. Jr. ;

Zhang, Q. .

Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Materials Science and Engineering, 73

[42] Synthesis and spectroscopic characterization of group II-B complexes of 2,2'-bipyridine [J].

Hernandez, RJ ;

Vazquez, R .

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 212 :171-CHED

[43] SYNTHESIS AND CHARACTERIZATION OF OXORUTHENIUM(IV) COMPLEXES THAT UTILIZE A 2,2'-BIQUINOLINE LIGAND [J].

KUBOW, SA ;

MARMION, ME ;

TAKEUCHI, KJ .

INORGANIC CHEMISTRY, 1988, 27 (16) :2761-2767

[44] Synthesis and crystal structure of bis(2,2′-bipyridine-N,N′)dichloromanganese(II) complex with free 2,2′-bipyridine [J].

Li, ZY ;

Xu, DJ ;

Nie, JJ ;

Wu, ZY ;

Wu, JY ;

Chiang, MY .

JOURNAL OF COORDINATION CHEMISTRY, 2002, 55 (10) :1155-1160

[45] Synthesis, Characterization and Crystal Structure of (2,2′-Bipyridine)(μ-maleato)copper(II) Dihydrate [J].

李震宇 ;

徐端钧 ;

史卫良 ;

陈德余 ;

吴景云 ;

蒋燕南 .

ChineseJournalofChemistry, 2002, (04) :390-394+297

[46] Synthesis and Characterization of Platinum(II) Complexes with 2,2′-Bipyridine Derivative Supporting Ligands [J].

Yang, Kwang Woon ;

Hwang, Hey Eun ;

Jung, Hee Sun ;

Kwak, Chee Hun ;

Lee, Ji Hoon ;

Jung, Sang-Chul ;

Ahn, Ho Geun ;

Chung, Min Chul .

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2011, 11 (08) :7331-7334

[47] Substitution reactions of cis-dichloro(2,2′-biquinoline)palladium(II) with amino acids [J].

Zaghal, Mukarram H. ;

Saeed, Manar S. Bani ;

Hamid, Amer A. G. Abdel ;

Ali, Basem F. .

ARABIAN JOURNAL OF CHEMISTRY, 2017, 10 :S3920-S3928

[48] (2,2′-bipyridine)bromodiimidazolecopper(II) bromide [J].

Xia, FY ;

Li, XH ;

Lei, XX .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 :M1955-M1956

[49] Diaqua(2,2′-bipyridine)malonatomanganese(II) [J].

Shen, L .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2003, 59 :M128-M129

[50] Bis(μ-2,2′-disulfanediyldibenzoato)bis[aqua(2,2′-bipyridine)nickel(II)] [J].

Liu, Zhengming ;

Qu, Botao ;

Yu, Jianghua ;

Yuan, Limin ;

Liu, Wenlong .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 :M1563-U760

← 1 2 3 4 5 →