SYNTHESIS AND CHARACTERIZATION OF CIS-(2,2'-BIPYRIDINE)(2,2'-BIQUINOLINE)DICHLORORUTHENIUM(II) AND ITS COORDINATION CHEMISTRY WITH IMIDAZOLE DERIVATIVES

被引：23

作者：

HEIJDEN, M ^{[1
]}

VANVLIET, PM ^{[1
]}

HAASNOOT, JG ^{[1
]}

REEDIJK, J ^{[1
]}

机构：

[1] LEIDEN UNIV,LEIDEN INST CHEM,GORLAEUS LABS,POB 9502,2300 RA LEIDEN,NETHERLANDS

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 24期

关键词：

D O I：

10.1039/dt9930003675

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of cis-[Ru(bipy)(bquin)Cl2] (bipy = 2,2'-bipyridine, bquin = 2,2'-biquinoline) with several imidazole derivatives have been studied. Substitution of only one chloride ligand takes place exclusively trans to bquin, resulting in the synthesis of cis- [Ru(bipy)(bquin)(L)Cl]PF6 (L = Him, 1-mim or 5-mim; Him = imidazole, 1-mim = 1-methylimidazole, 5-mim = 5-methylimidazole). This substitution preference for imidazoles indicates that bquin has a stronger electronic trans influence than bipy, and that the steric effects of bquin do not appear to obstruct the approach of a substituting ligand. By substitution of the second chloride the compounds cis-[Ru(bipy)(bquin)L2][PF6]2 and cis-[Ru(bipy)(bquin)(1-mim)-(HIM)][PF6]2 were isolated. The properties of the compounds have been studied by H-1 NMR spectroscopy and electrochemistry. The studies show that cis-[Ru(bipy)(bquin)Cl2] incorporates potential covalent binding properties for biomolecules like histidine and DNA.

引用

页码：3675 / 3679

页数：5

共 50 条

[31] CYCLOMETALLATED DERIVATIVES OF 2,2'-BIPYRIDINE COMPLEXES [J].

CONSTABLE, EC ;

LEESE, TA ;

HOUSECROFT, CE .

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 194 :114-INOR

[32] Pyrene derivatives of 2,2′-bipyridine as models for asphaltenes:: Synthesis, characterization, and supramolecular organizations [J].

Tan, Xiaoli ;

Fenniri, Hicham ;

Gray, Murray R. .

ENERGY & FUELS, 2008, 22 (02) :715-720

[33] Regioselective functionalization of 2,2′-bipyridine and transformations into unsymmetric ligands for coordination chemistry [J].

Norrby, T ;

Borje, A ;

Zhang, L ;

Akermark, B .

ACTA CHEMICA SCANDINAVICA, 1998, 52 (01) :77-85

[34] TRIPLET-STATE FEATURES OF 2,2'-BIQUINOLINE AND DERIVATIVES [J].

LEENSTRA, WR ;

BEVAN, AJ ;

THUMMEL, RP .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (23) :8506-8508

[35] THE SYNTHESIS OF BIS-(2,2'-BIPYRIDINE) [4,4'-DI(HEXADECYLOXYCARBONYL)-2,2'-BIPYRIDINE] RUTHENIUM(II) AND ITS APPLICATION FOR PHOTOLYSIS OF WATER [J].

PARK, YT ;

NOH, SG .

BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1994, 15 (11) :922-924

[36] A 2,2′-bipyridine coordination complex of [ICl2]+ [J].

Shaw, Andrew J. M. ;

Corbo, Robert ;

Wilson, David J. D. ;

Dutton, Jason L. .

DALTON TRANSACTIONS, 2015, 44 (34) :15083-15087

[37] Coordination modes of salicylaldehyde derivatives in the ruthenium(II) nitrosyl and bis(2,2′-bipyridine) ruthenium(II) complexes [J].

Chen, Chong ;

Ji, Jiao ;

Wang, Chang-Jiu ;

Jia, Ai-Quan ;

Zhang, Qian-Feng .

JOURNAL OF COORDINATION CHEMISTRY, 2020, 73 (08) :1306-1313

[38] cis-Dichlorobis(2,2′-biquinoline)iridium(III) hexafluorophosphate [J].

Yoshikawa, N ;

Sakamoto, J ;

Kanehisa, N ;

Kai, Y ;

Matsumura-Inoue, T ;

Takashima, H ;

Tsukahara, K .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2003, 59 :M551-M552

[39] Synthesis and Characterization of Platinum(II) Complexes with Various Substituted 2,2′-Bipyridine Ligands [J].

Son, Seokhwan ;

Lee, Hwan Gyu ;

Lee, Nopl ;

Ryu, Minwoo ;

Kwak, Cheehun ;

Lee, Jihoon ;

Ahn, Hogeun ;

Chung, Minchu .

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2016, 16 (02) :2028-2031

[40] (2,2′-biquinoline)tetracarbonylmolybdenum(0) [J].

Muir, Kathleen J. ;

McQuillan, Geoffrey P. ;

Harrison, William T. A. .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 :M2452-U172

← 1 2 3 4 5 →